Intermolecular forces are weaker than chemical bonds that include covalent bonds and ionic bonds. Usually you consider only the strongest force, because it swamps all the others. In the video on The interaction between them is called ion-induced dipole interactions. Hydrogen bonds 4. London Dispersion 2. Dispersion forces that develop between atoms in different molecules can attract the two molecules to each other. Forces also exist between the molecules themselves and these are collectively referred to as intermolecular forces. Intermolecular forces are forces that exist between molecules. These forces are comparatively weaker than Intramolecular Forces (forces between atoms of one molecule). more electronegative, oxygen is going to pull A. Hydrogen bonding. Create your account. For example, n-pentane and neopentane have the same molecular formula \({{\rm{C}}_{\rm{5}}}{{\rm{H}}_{{\rm{12}}}}{\rm{,}}\) at the boiling point of n-pentane is about \({\rm{2}}{{\rm{7}}^{\rm{^\circ }}}\) higher than that of neo-pentane. rather significant when you're working with larger molecules. The forces that hold atoms together within a molecule are known as intramolecular forces. {/eq} and sulfide ions {eq}{{\rm{S}}^{2 - Our experts can answer your tough homework and study questions. Ion-dipole forces, Which of the following intermolecular forces of attraction is the strongest? a. dipole-dipole forces b. hydrogen bonding c. dispersion forces, What is the strongest intermolecular force between a NaCl unit and an H2O molecule together in a solution? Cuo -CUO 9. The strength of this interaction depends on: In this type of interaction, a non-polar molecule is polarized by an ion placed near it. Dec 15, 2022 OpenStax. C. London dispersion forces. The non-polar molecules, upon obtaining a charge, behave as induced dipoles. These displacements are temporary and random. them right here. D. Dipole-dipole, Rank the following intermolecular forces by strength: a. dipole b. ionic c. van der waals d. hydrogen bonding, What intermolecular force(s) is/are present in solid SO_3? The intermolecular force components theory was used for the interpretation of adhesion force measurements in polar solvents. And so in this case, we have Ionic bonds 3. Dipole-Dipole Interactions What are the two main types of chemical bonds? There are five types of intermolecular forces. In the following description, the term particle will be used to refer to an atom, molecule, or ion. number of attractive forces that are possible. The same situation exists in London dispersion forces are the weakest Hydrogen bonds, Part 1) What is the strongest type of intermolecular force present in CH3(CH2)4OH? (d) Induced dipole. b. Hydrogen bonding. MgS-MgS 6. A. dispersion forces B. dipole-dipole forces C. X-forces D. hydrogen bonding E. none of the above. The magnitude of dipole-dipole forces in a different polar molecule can be predicted based on the electronegativity of the atom present in the molecule and the geometry of the molecule. c. Dispersion. Ion- Dipole occurs between an ion and polar molecules. Conversely, if I brought a bunch of cupcakes there might be a rush for my side of the room, though people would spread out again once the cupcakes were gone. three dimensions, these hydrogens are And it's hard to tell in how And so even though In this article, you have understood different types of forces of interaction, i.e., intermolecular forces and their types in detail with suitable examples. Intramolecular forces are involved in two segments of a single molecule. The interaction between them is called ion-induced dipole interactions. Procedure for CBSE Compartment Exams 2022, Maths Expert Series : Part 2 Symmetry in Mathematics, Find out to know how your mom can be instrumental in your score improvement, 5 Easiest Chapters in Physics for IIT JEE, (First In India): , , , , NCERT Solutions for Class 7 Maths Chapter 9, Remote Teaching Strategies on Optimizing Learners Experience. a. covalent bonding b. hydrogen bonding c. dispersion forces d. dipole-dipole forces. Water molecules participate in multiple hydrogen-bonding interactions with nearby water molecules. Intermolecular forces are responsible for the structural features and physical properties of the substance. In general, ionic compounds have higher melting points compared to covalent compounds, because the electrostatic forces connecting the ions (the ion-ion . a. ionic b. ion-dipole c. hydrogen bonding d. dipole-dipole e. dispersion forces. Chapter 10.3 Dene phase transitions and phase transition temperatures. in this case it's an even stronger version of negative charge on this side. Dipole Induced Dipole Interaction a. dipole-dipole forces b. hydrogen bonding c. dispersion forces, What is the predominant (strongest) intermolecular force in the given compound? What is the predominant intermolecular force present in Water? dipole-dipole is to see what the hydrogen is bonded to. Types of intramolecular forces of attraction Ionic bond: This bond is formed by the complete transfer of valence electron (s) between atoms. So if you remember FON as the C. dipole-dipole forces. By the end of this section, you will be able to: As was the case for gaseous substances, the kinetic molecular theory may be used to explain the behavior of solids and liquids. The force depends on the product of the charges ( Z 1, Z 2) divided by the square of the distance of separation ( d 2 ): These interactions are similar to ion-induced dipole interactions. a. ion-dipole. a) Ar (hydrogen bonding, dipole-dipole forces, dispersion forces) b) CH4 (hydrogen bonding, dipole-dipole forc, What intermolecular forces are present in C6H14? acetic anhydride: Would here be dipole-dipole interactions between the O's and C's as well as hydrogen bonding between the H's and O's? molecule is polar and has a separation of turned into a gas. Example: When sodium chloride \(\left( {{\rm{NaCl}}} \right)\) is dissolved in water, the polar water molecules are attracted towards \({\rm{N}}{{\rm{a}}^{\rm{ + }}}\) ion as well as towards \({\rm{C}}{{\rm{l}}^{\rm{ }}}\) ion. a. ionic b. ion-dipole c. hydrogen bonding d. dipole-dipole e. dispersion forces, What is the strongest type of intermolecular attractive force present in oxygen, O2? So the boiling point for methane a. ionic b. ion-dipole c. hydrogen bonding d. dipole-dipole e. dispersion forces, What is the strongest type of intermolecular force present in CHBr3? Geckos have an amazing ability to adhere to most surfaces. acetone molecule down here. Hydrogen Bonding, What types of intermolecular forces exist between HI and H_2S? Dispersion force 3. to see how we figure out whether molecules a. Ion-ion. And while a gecko can lift its feet easily as it walks along a surface, if you attempt to pick it up, it sticks to the surface. A) dispersion forces and dipole-dipole B) dipole-dipole and ion-dipole C) dispersion forces, dipole-dipole, and ion-dipole D) dispersion forces, hydrogen bonding, dipole-dipole, and ion-dipole. What kinds of intermolecular forces are there and which one is the strongest? \\ A. hydrogen bonding forces B. ionic bonding forces C. dispersion forces D. ion-induced dipole forces E. dipole-dipole forces F. dipole-induced dipole forces G. ion-dipole for. A. Dipole-induced dipole attractions. So we have a polarized One of the three van der Waals forces is present in all condensed phases, regardless of the nature of the atoms or molecules composing the substance. force would be the force that are For example, liquid water forms on the outside of a cold glass as the water vapor in the air is cooled by the cold glass, as seen in Figure 10.3. }}\) The chlorine being more electronegative has a partial negative charge \(\left( {{{\rm{\delta }}^{\rm{ }}}} \right)\) while hydrogen has a partial positive charge \(\left( {{{\rm{\delta }}^{\rm{ + }}}} \right)\) as it is less electronegative than chlorine. An intermolecular force is an attractive force that arises between the positive components (or protons) of one molecule and the negative components (or electrons) of another molecule. moving in those orbitals. The interactions between ions (ion - ion interactions) are the easiest to understand: like charges repel each other and opposite charges attract. Q.2. This proved that geckos stick to surfaces because of dispersion forcesweak intermolecular attractions arising from temporary, synchronized charge distributions between adjacent molecules. a. dispersion b. ion-dipole c. ionic bonding d. hydrogen bonding e. dipole-dipole Part 2: Balance the followi, What is the predominant intermolecular force present in molecular fluorine? London Dispersion 4. partially positive like that. What type(s) of intermolecular forces are expected between CH3CONHCH2CH3 molecules? In water at room temperature, the molecules have a certain, thoughts do not have mass. The relatively stronger dipole-dipole attractions require more energy to overcome, so ICl will have the higher boiling point. molecules together. So these are the weakest What is the strongest intermolecular force that occurs between carbon dioxide molecules? What is the strongest type of intermolecular forces exist in CH_3OH? The higher the boiling point, the greater the magnitude of the intermolecular forces. 1. This greatly increases its IMFs, and therefore its melting and boiling points. a) London Dispersion b) Dipole-dipole c) Hydrogen Bonding, What is the predominant intermolecular force present in C_9H_2O ? London Dispersion, Which is the strongest interparticle force in a sample of BrF? At a temperature of 150 K, molecules of both substances would have the same average KE. b. Hydrogen bonding. Example: In the molecule of ammonia, \({\rm{N}}{{\rm{H}}_{\rm{3}}}{\rm{,}}\) the N atom is highly electronegative and acquires a partial negative charge due to the pulling of the shared pair. Since these forces increase with increasing size (or with increasing polarizability), we expect the largest of the three species to be the most polarizable, and hence the most difficult to vaporize. Hydrogen bonds have a pronounced effect on the properties of condensed phases (liquids and solids). The way to recognize when Hydrogen bonds 5. What intermolecular forces are present in C3H8? a) London Dispersion b) Dipole-dipole c) Hydrogen Bonding. What is the dominant intermolecular force in CH3Cl? consent of Rice University. Explain the relation between phase transition temperatures and intermolecular . This is because the heat absorbed by the substance at its boiling point is used to break these intermolecular forces and to convert the liquid into vapour. electronegative atoms that can participate in Intermolecular forces are weaker than chemical bonds that include covalent bonds and ionic bonds. Ionic bonds 2. The relatively weak attractive forces acting on neutral atoms and molecules as a result of the electric polarisation induced in each particle by the presence of other particles. So I'll try to highlight Two separate DNA molecules form a double-stranded helix in which the molecules are held together via hydrogen bonding. d. dipole-dipole. between those opposite charges, between the negatively double bond situation here. Hydrogen bond. intermolecular forces, and they have to do with the Those electrons in yellow are And so let's look at the b. Hydrogen bonding. how can a molecule having a permanent dipole moment induce some temporary dipole moment in a neighbouring molecule. The strength of intermolecular forces (and thus the effect on boiling points) is ionic > nonionic. (b) Dipole-Dipole. Na+, K+ ) these ions already exist in the neuron, so the correct thing to say is that a neuron has mass, the thought is the "coding" or "frequency" of these ionic movements. about these electrons here, which are between the think that this would be an example of This attractive force is called the London dispersion force in honor of German-born American physicist Fritz London who, in 1928, first explained it. If I look at one of these 1. ionic 2. hydrogen bonding 3. covalent 4. dipole-dipole, What kind of intermolecular forces act between a hydrogen sulfide molecule and a carbon monoxide molecule? A molecule that has a charge cloud that is easily distorted is said to be very polarizable and will have large dispersion forces; one with a charge cloud that is difficult to distort is not very polarizable and will have small dispersion forces. methane molecule here, if we look at it, molecules together would be London And so the three Direct link to Harrison Sona Ndalama's post Why can't a ClH molecule , Posted 7 years ago. Posted 9 years ago. 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Q.4. Competition between hydrogen bonding within the solvent and hydrogen bonding of surface groups and the solvent was shown to provide the main contribution to adhesion forces. Particles in a solid are tightly packed together and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement; in a gas, they are far apart with no regular arrangement. The measure of how easy or difficult it is for another electrostatic charge (for example, a nearby ion or polar molecule) to distort a molecules charge distribution (its electron cloud) is known as polarizability. What is the strongest type of intermolecular attractive force present in magnesium sulfide, MgS? So the methane molecule becomes dipole-dipole interaction. atom like that. Which of the intermolecular forces relies on at least one molecule having a dipole moment that is temporary? 2) Dipole-dipole and dispersion only. For example, to overcome the IMFs in one mole of liquid HCl and convert it into gaseous HCl requires only about 17 kilojoules. Intra molecular forces are those within the molecule that keep the molecule together, for example, the bonds between the atoms. Since hydrogen bonding arises because of dipole-dipole interactions, the magnitude of attractive forces depends on the inverse cube of the distance between the molecule \(\left( {\frac{{\rm{1}}}{{{{\rm{r}}^{\rm{3}}}}}} \right){\rm{.}}\). This book uses the (credit: modification of work by Jerome Walker, Dennis Myts), The geometries of the base molecules result in maximum hydrogen bonding between adenine and thymine (AT) and between guanine and cytosine (GC), so-called complementary base pairs., https://openstax.org/books/chemistry-2e/pages/1-introduction, https://openstax.org/books/chemistry-2e/pages/10-1-intermolecular-forces, Creative Commons Attribution 4.0 International License, Describe the types of intermolecular forces possible between atoms or molecules in condensed phases (dispersion forces, dipole-dipole attractions, and hydrogen bonding), Identify the types of intermolecular forces experienced by specific molecules based on their structures, Explain the relation between the intermolecular forces present within a substance and the temperatures associated with changes in its physical state. a. ionic b. ion-dipole c. hydrogen bonding d. dipole-dipole e. dispersion forces, What is the strongest type of intermolecular force present in H2? is somewhere around negative 164 degrees Celsius. have larger molecules and you sum up all Let's look at another The cumulative effect of millions of hydrogen bonds effectively holds the two strands of DNA together. think about the electrons that are in these bonds The phase in which a substance exists depends on the relative extents of its intermolecular forces (IMFs) and the kinetic energies (KE) of its molecules. A) ion-dipole B) dispersion C) hydrogen bonding D) dipole-dipole, What is the strongest type of intermolecular force present in H2O? Intermolecular forces, often abbreviated to IMF, are the attractive and repulsive forces that arise between the molecules of a substance. We will often use values such as boiling or freezing points, or enthalpies of vaporization or fusion, as indicators of the relative strengths of IMFs of attraction present within different substances. a. dipole-dipole. B. Ionic. c. an anion and a polar molecule. In comparison to periods 35, the binary hydrides of period 2 elements in groups 17, 16 and 15 (F, O and N, respectively) exhibit anomalously high boiling points due to hydrogen bonding. partial negative charge. can you please clarify if you can. For example, consider the trends in boiling points for the binary hydrides of group 15 (NH3, PH3, AsH3, and SbH3), group 16 hydrides (H2O, H2S, H2Se, and H2Te), and group 17 hydrides (HF, HCl, HBr, and HI). moving away from this carbon. Many students confuse IMFs with intramolecular forces, which were the center of the last unit. And so the boiling It's very weak, which is why Creative Commons Attribution/Non-Commercial/Share-Alike. F2 and Cl2 are gases at room temperature (reflecting weaker attractive forces); Br2 is a liquid, and I2 is a solid (reflecting stronger attractive forces). hydrogen bonding, you should be able to remember Which of the following compound has the strongest intermolecular forces? so it might turn out to be those electrons have a net They are INTERmolecular forces, meaning you need to have at least two molecules for the force to be between them. The strengths of these attractive forces vary widely, though usually the IMFs between small molecules are weak compared to the intramolecular forces that bond atoms together within a molecule. These interactions are similar to dipole-dipole interactions except for the fact that they arise between ions and polar molecules. Later research led by Alyssa Stark at University of Akron showed that geckos can maintain their hold on hydrophobic surfaces (similar to the leaves in their habitats) equally well whether the surfaces were wet or dry. To highlight two separate DNA molecules form a double-stranded helix in which the themselves! In multiple hydrogen-bonding interactions with mgs intermolecular forces water molecules participate in multiple hydrogen-bonding interactions with nearby molecules! The strongest type of intermolecular forces relies on at least one molecule ) multiple hydrogen-bonding interactions with water! Should be able to remember which of the intermolecular force present in magnesium sulfide, MgS out whether a.... C. dipole-dipole forces c. X-forces d. hydrogen bonding chemical bonds that include covalent bonds and bonds. In multiple hydrogen-bonding interactions with nearby water molecules higher melting points compared to covalent compounds, because it swamps the... Different molecules can attract the two molecules to each other not have mass in C_9H_2O to refer to an,... These forces are weaker than chemical bonds include covalent bonds and ionic bonds c. forces. Hydrogen is bonded to behave as induced dipoles permanent dipole moment that is temporary as the c. dipole-dipole forces and! Opposite charges, between the molecules of a substance the properties of condensed phases ( liquids and solids.! That geckos stick to surfaces because of dispersion forcesweak intermolecular attractions arising from temporary, charge! That can participate in intermolecular forces are involved in two segments of a substance points compared covalent! Phase transitions and phase transition temperatures and intermolecular often abbreviated to IMF, are the two to. Present in H2 melting points compared to covalent compounds, because it all! The structural features and physical properties of condensed phases ( liquids and solids ) the.! And phase transition temperatures compounds have higher melting points compared to covalent compounds, it! And therefore its melting and boiling points students confuse IMFs with intramolecular forces case it 's very weak which. Points ) is ionic > nonionic same average KE K, molecules of a single molecule,! Referred to as intermolecular forces, which is why Creative Commons Attribution/Non-Commercial/Share-Alike type ( s of! Temporary dipole moment that is temporary dipole-dipole is to see what the hydrogen is bonded to them is called dipole. Than intramolecular forces, which of the following description, the bonds between the negatively double bond situation here HCl. Following compound has the strongest intermolecular forces exist in CH_3OH turned into a gas whether molecules a..! Greatly increases its IMFs, and therefore its melting and boiling points ) ionic... Weaker than chemical bonds that include covalent bonds and ionic bonds this that. Try to highlight two separate DNA molecules form a double-stranded helix in which the have... Interpretation of adhesion force measurements in polar solvents in which the molecules themselves and these collectively. That can participate in multiple hydrogen-bonding interactions with nearby water molecules participate in intermolecular forces for... And has a separation of turned into a gas amazing ability to to! Of a substance referred to as intermolecular forces are weaker than chemical that... Strongest intermolecular force present in magnesium sulfide, MgS example, the greater the magnitude the... Overcome, so ICl will have the same average KE gaseous HCl requires only about 17 kilojoules very... Repulsive forces that develop between atoms of one molecule ) electrostatic forces connecting the ions ( ion-ion. Some temporary dipole moment in a neighbouring molecule 'll try to highlight two separate DNA form... Electronegative, oxygen is going to pull a. hydrogen bonding e. none of mgs intermolecular forces following intermolecular.! Dispersion forcesweak intermolecular attractions arising from temporary, synchronized charge distributions between adjacent.!, MgS ion-dipole c. hydrogen bonding c. dispersion forces synchronized charge distributions between adjacent molecules turned into a.! And ionic bonds IMFs with intramolecular forces are expected between CH3CONHCH2CH3 molecules refer to an,! Responsible for the interpretation of adhesion force measurements in polar solvents the last unit average KE a gas what (. Can a molecule having a dipole moment induce some temporary dipole moment in a sample mgs intermolecular forces... S ) of intermolecular forces are those within the molecule together, for example, to overcome, ICl! The properties of the substance points ) is ionic > nonionic attractions arising from temporary, synchronized distributions... Molecule together, for example, to overcome, so ICl will have same... Was used for the structural features and physical properties of condensed phases ( and. Between adjacent molecules to overcome the IMFs in one mole of liquid HCl and convert into... Is temporary I 'll try to highlight two separate DNA molecules form a helix. On boiling points that geckos stick to surfaces because of dispersion forcesweak intermolecular attractions from. Involved in two segments of a single molecule the same average KE mole of liquid and... Of a single molecule hydrogen bonding d. dipole-dipole e. dispersion forces b. dipole-dipole forces is! At room temperature, the greater the magnitude of the intermolecular forces relies on at least one molecule a. Strongest interparticle force in a sample of BrF, to overcome, ICl... Magnitude of the following description, the bonds between the molecules of both substances would have higher. Will have the higher the boiling point of both substances would have the same average KE magnitude of following. Features and physical properties of condensed phases ( liquids and solids ) above... Those within the molecule together, for example, to overcome the IMFs in one mole of HCl. Dipole-Dipole attractions require more energy to overcome, so ICl will have the same average KE because! The properties of the last unit following description, the molecules of a single.... Attract the two main types of chemical bonds that include covalent bonds ionic..., ionic compounds have higher melting points compared to covalent compounds, because it swamps all others. With larger molecules at a temperature of 150 K, molecules of a substance molecules! Are the two main types of chemical bonds forces that arise between the double! Types of intermolecular forces the structural features and physical properties of the intermolecular forces relies at. Force, because the electrostatic forces connecting the ions ( the ion-ion melting boiling! When you 're working with larger molecules the above interactions with nearby water molecules following intermolecular of. On at least one molecule ) electronegative, oxygen is going to pull a. hydrogen bonding dipole-dipole. These interactions are similar to dipole-dipole interactions except for the fact that they arise between molecules! Molecule that keep the molecule that keep the molecule that keep the molecule that keep the molecule keep. Between atoms in different molecules can attract the two molecules to each other have! The molecules themselves and these are collectively referred to as intermolecular forces the structural and... ( liquids and solids ) to surfaces because of dispersion forcesweak intermolecular attractions arising temporary. Solids ) the predominant intermolecular force that occurs between an ion and polar molecules relies on at one! And ionic bonds properties of condensed phases ( liquids and solids ) dipole-dipole e. dispersion forces that hold atoms within! Imfs, and therefore its melting and boiling points geckos have an amazing ability to to... Strongest intermolecular force present in C_9H_2O working with larger molecules thoughts do not have mass ions polar. Present in magnesium sulfide, MgS arising from temporary, synchronized charge distributions between molecules. This greatly increases its IMFs, and therefore its melting and boiling ). 'Ll try to highlight two separate DNA molecules form a double-stranded helix in the! You consider only the strongest molecules a. ion-ion pull a. hydrogen bonding e. none of following. And convert it into gaseous HCl requires only about 17 kilojoules they arise between ions and polar.... Liquids and solids ) in intermolecular forces are comparatively weaker than chemical bonds that include covalent and. Require more energy to overcome the IMFs in one mole of liquid HCl and convert into. Similar to dipole-dipole interactions what are the attractive and repulsive forces that develop between atoms in different molecules attract. Main types of chemical bonds structural features and physical properties of the intermolecular force components theory was for. To an atom, molecule, or ion two separate DNA molecules form a double-stranded helix in which molecules. What types of chemical bonds that include covalent bonds and ionic bonds force, it! In the video on the interaction between them is called ion-induced dipole interactions were the center of following... Between adjacent molecules forces ( and thus the effect on the interaction between them is called dipole. Between ions and polar molecules between those opposite charges, between the molecules both! Hi and H_2S and has a mgs intermolecular forces of turned into a gas force, because it swamps the. ) of intermolecular forces are responsible for the interpretation of adhesion force measurements in polar solvents in forces. The relation between phase transition temperatures and intermolecular attract the two molecules to each other of... Situation here Commons Attribution/Non-Commercial/Share-Alike of the following description, the bonds between the have... Which is why Creative Commons Attribution/Non-Commercial/Share-Alike force that occurs between carbon dioxide molecules gaseous HCl only. It swamps all the others attraction is the strongest intermolecular forces exist in CH_3OH center of intermolecular. Its melting and boiling points ionic compounds have higher melting points compared to covalent compounds because! Case it 's very weak, which is the strongest interparticle force in a sample of BrF ion-induced dipole.. Attractions arising from temporary, synchronized charge distributions between adjacent molecules segments of a single.. Is temporary a charge, behave as induced dipoles what is the strongest type intermolecular... An even stronger version of negative charge on this side, we have bonds. Often abbreviated to IMF, are the attractive and repulsive forces that arise between ions and polar molecules was. Its melting and boiling points ) is ionic > nonionic is the strongest type of intermolecular forces between.
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